Controllably creating patterned semiconductor junctions in thin planar materials could enable ultrathin microelectronics for numerous applications such as in smartphones, next-generation solar cells, and lighting.
Junctions of 2D semiconductors could enable next-generation photovoltaics, lighting, and electronics. For example, current electronics rely on 10-nm-wide junctions between different semiconductors in 3D crystals. Controllable synthetic methods are needed to create narrow junctions between different 2D materials.
Now, researchers at Oak Ridge National Laboratory have developed a process for creating these junctions between different 2D semiconductors in arbitrary patterns using standard electron beam lithography techniques.
Single layers of molybdenum diselenide (MoSe2) crystals less than a nanometer thick were first patterned with a silicon oxide mask and then exposed to laser-vaporised sulfur. The sulfur atoms replaced the selenium atoms in the exposed regions, selectively converting MoSe2 to molybdenum disulfide (MoS2).
Chemical mapping with Raman spectroscopy confirmed the chemical conversion was uniform. Atomic-resolution electron microscopy revealed that the junctions between the different semiconductors were only 5 nm wide. Patterning such sharp junctions could facilitate a range of ultrathin devices from flexible consumer electronics to more efficient solar cells.